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The rate constant, k 0 , is obtained from the current density according to the following relation. The Arrhenius plots for the rate constants are shown in Fig. The rate constants and the activation energies obtained from the Arrhenius plots are listed in Table III. The activation energies for the viscosity are also listed. It has been demonstrated that the diffusion of a charged species is influenced by coulombic interaction between the charged species and the ions composing ionic liquids.

Nonaqueous Electrochemistry

In addition, the coulombic interaction is found to be dependent on the charge density of the species by comparison between two metal complexes with different sizes. It has been also verified that the coulombic interaction between a redox couple and the ions of ionic liquids dominantly determines the apparent reaction entropy for the redox reaction. User Name Password Sign In. Figure 1. Previous Section Next Section. Figure 2. View this table: In this window In a new window. Table I. Figure 3.

Table II. Figure 4. Figure 5. Table III. Figure 6. Figure 7. Randles-type equivalent circuit for analysis of impedance data. Figure 8. Figure 9. Table IV. Previous Section. Tachikawa N. Solid-State Lett. Silvester D. C , , CrossRef Google Scholar. Interscience, New York, p Hills GJ Reference electrodes in nonaqueous solutions. Academic, New York, p Juillard J J Chim Phys Bertocci U Z Elektrochem Izutsu K Electrochemistry in Nonaqueous Solutions, 2nd edn.

Academic, New York, Chapter 1. Badoz-Lambling J, Cauquis G Analytical aspects of voltammetry in non-aqueous solvents and melts. Wiley, New York, p References 1. Pierce A. Pulpal injury: Pathology, diagnosis and periodontal reactions. Love R. Intraradicular space: What happens within roots of infected teeth?

Electrochemistry In Nonaqueous Solutions, 2Nd Edition

Invasion of dentinal tubules by oral bacteria. Oral Biol. Sen B. Observation of bacteria and fungi in infected root canals and dentinal tubules by SEM. Siqueira J. Patterns of microbial colonization in primary root canal infections. Oral Surg. Oral Med. Oral Pathol.

Oral Radiol. Rocha C. Biofilm on the apical region of roots in primary teeth with vital and necrotic pulps with or without radiographically evident apical pathosis. Foschi F. Raisingani D. Kiran S. Frank A. Calcium hydroxide: The ultimate medicament?


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Gencoglu N. Antibacterial efficacy of root canal medicaments. Nihon Univ. Disinfection by calcium hydroxide pastes of dentinal tubules infected with two obligate and one facultative anaerobic bacteria. Enterococcus faecalis—A mechanism for its role in endodontic failure.

Chivatxaranukul P. Dentinal tubule invasion and adherence by Enterococcus faecalis. Good M. A survey of various endodontic procedures related to mineral trioxide aggregate usage by members of the Australian Society of Endodontology. Madarati A.

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Preference and usage of intracanal medications during endodontic treatment. Saudi Med. Abbott P. Medicaments: Aids to success in endodontics. Part 2. Clinical recommendations. Rehman K. Calcium ion diffusion from calcium hydroxide-containing materials in endodontically-treated teeth: An in vitro study. Athanassiadis B.

Electrochemistry in Nonaqueous Solutions (2nd ed.)

The use of calcium hydroxide, antibiotics and biocides as antimicrobial medicaments in endodontics. S1 :S64—S Orstavik D. Root canal disinfection: A review of concepts and recent developments. Sundqvist G. Microbiologic analysis of teeth with failed endodontic treatment and the outcome of conservative re-treatment. Fungi in endodontic infections. Robert G. Apical diffusion of calcium hydroxide in an in vitro model. Elimination of Candida albicans infection of the radicular dentin by intracanal medications.

An in vitro study of the antimicrobial activity of some endodontic medicaments and their bases using an agar well diffusion assay. Chirife J. In vitro anti-microbial activity of concentrated polyethylene glycol solutions.

Agents Chemother. An in vitro study of the antimicrobial activity of some endodontic medicaments against Enterococcus faecalis biofilms. In vitro study of the inactivation by dentine of some endodontic medicaments and their bases. Teoh Y. The influence of aqueous and PEG solvent vehicles on hydroxyl ion release from calcium hydroxide medicaments. Fava L. Calcium hydroxide pastes: Classification and clinical indications. Lana P. Antimicrobial activity of calcium hydroxide pastes on Enterococcus faecalis cultivated in root canal systems. Lima R.

Effectiveness of calcium hydroxide-based intracanal medicaments against Enterococcus faecalis. Guerreiro-Tanomaru J. Release and diffusion of hydroxyl ion from calcium hydroxide-based medicaments. Estrela C.